boiling point of water...cooling systems | FerrariChat

boiling point of water...cooling systems

Discussion in 'Technical Q&A' started by smg2, Apr 11, 2007.

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  1. smg2

    smg2 F1 World Champ
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    Just a quick note here, I needed to replace the old radiator cap and noticed my old one is a 1.1bar cap and the one the WSM specs should be a 0.9bar cap.

    as most know water boils at different temps based on pressure, the difference between the above is thus,
    1.1bar = 16.7psi = 216*F
    0.9bar = 13.23psi = 206 *F

    the factory cap lowers the boiling point of water below std atmosphere of 212*F. I don't know why and wonder if it's the cause of many hot running problems. I'll see what I can dig up.
     
  2. ernie

    ernie Two Time F1 World Champ
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    I think it has to do with that and the water pump not moving enough water through the radiators.
     
  3. vincent355

    vincent355 F1 Veteran
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    I think that this is the pressure at which the rad cap will safety valve out extra pressure. Though higher pressures will cause higher boiling temperatures, I don't think that letting vapor out at a lower pressure will reduce the boiling point since you are venting out to a higher pressure atmosphere.

    Now if your car was at elevation that is a different story.

    heat exchage is most likely your problem, not enough of it.
     
  4. smg2

    smg2 F1 World Champ
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    see i don't know, a 0.9bar cap is less than std atmosphere so you may as well not even have one. but there's got to be more to it, pressure or vacuum has a role here, still looking.
     
  5. John Harry

    John Harry Formula Junior

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    Isn’t that 0.9 bar ABOVE atmospheric pressure?
     
  6. smg2

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  7. eric355

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  8. James_Woods

    James_Woods F1 World Champ

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    Surely you are not running just pure water? What about the ethylene glycol?

    And I don't get this "venting out to a higher atmospheric pressure", either...I thought venting only works from high pressure to low pressure?

    I thought that most cars nowadays could probably tolerate coolant temps in the range of 230 - 235 degrees or more before venting into the catch tank.
     
  9. dozzina

    dozzina F1 World Champ
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    The cap adds pressure to the ambient pressure (varies with your elevation.) A 1 bar cap at sea level at normal barametric pressure would have 14.7psi + 14.7psi = 29.4psi of absolute pressure. Pure water would boil at about 249F in this situation.
     
  10. Hessian

    Hessian Formula Junior

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    I think he means that the cap will hold against net pressure in the cooling system of 0.9bar. The outside ambient pressure is apx 1.0bar. Thus, a 0.9bar cap holds the cooling system to 1.9bar. The forces on the cap would be ballanced if the atm is 1.0bar and the total vapor pressure of the system is also 1.0bar (ie it's cold and you've just closed the cap). As the system heats, the pressure inside increases. The cap's seal will hold until there is a net pressure differential of 0.9bar, then, as designed, it blows. Because the coolant was in the liquid state under >1.0bar at a temperature above it's boiling point at 1.0bar, it will boil almost explosively when the pressure is rapidly reduced to 1.0bar (say, if you uncapped a hot system) as the liquid rapidly undergoes a first order phase transition to gas.

    Edit - I need to learn to type faster.
     
  11. Rifledriver

    Rifledriver Three Time F1 World Champ

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    It's about as basic as physics gets.
     
  12. smg2

    smg2 F1 World Champ
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    I see what your saying but once you 'cap' the system it shouldn't matter what the pressure outside it is, much like a vacuum, unless the coolant system here bleeds in air. a 0.9bar cap will vent once the pressure inside the system hits that level which is less than 1.0 at sea level, it actually equivalent to an elevation 3000ft (0.9). water when heated to 200*F exerts a pressure of 16~18psi, the cap acts as a safety valve for the pressure.
     
  13. Rifledriver

    Rifledriver Three Time F1 World Champ

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    The cap valve is most certainly operating against exterior pressure.


    Physics 1A
     
  14. dozzina

    dozzina F1 World Champ
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    If you lived in a vacuum, this would be true. The only reference pressure available to the cap is the external, ambient pressure. It holds the contents at a fixed pressure above this. Using the one bar cap above, at 4000 ft altitude, atmospheric pressure is about 12.7psi. 12.7psi plus 14.7psi for the cap means that the absolute pressure in your cooling system is 27.4psi, and your pure water will boil at about 245F.
     
  15. smg2

    smg2 F1 World Champ
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    okay, then why when testing the caps pressure it's only tested to 15psi? and not the additive result?
     
  16. smg2

    smg2 F1 World Champ
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    here's another trick, does the cap have a vacuum release? there is no overflow tank, so if it did it would draw in air when cooling down.
     
  17. dozzina

    dozzina F1 World Champ
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    Because every pressure gage you own is calibrated to read 0 at ambient pressure, since all of them use ambient pressure as a reference. This is true for your tire pressure gages, the gage on your shop compressor, your blood pressure gage, your A/C manifold gage, etc. All of them. Even your vacuum gage. Just because your tire pressure gage reads zero before it is held up to the tire stem does not mean that there is no air pressure around you. It would be difficult to breath if that were the case.


    (OK, I happen to own one gage that reads 0 at a pressure of absolute 0, though it's never read that low. It's a specialty instrument you are unlikely to have.)
     
  18. smg2

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    I understand that, really I do. what I'm trying to get is that the cooling system is a 'closed' system, it's pressure is independent of the atmosphere outside.

    water when heated expands, and at about 200*F its around 17psi or 31.7psi absolute calculating in the atmosphere. that would equate to a 2.15bar absolute and that's an open system. a 0.9 + 1.0 is only 1.9 still lower than the open system.
     
  19. kompressor

    kompressor Formula Junior

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    redline makes a cool product its called water wetter, put that in with the next coolant change, they advertise a 20 degree drop in tempurature,

    supposedly it transfers more heat than water alone can id say check it out, i havent checked but royal purple may also make something similar
     
  20. Rifledriver

    Rifledriver Three Time F1 World Champ

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    Why are we trying to reinvent the wheel?

    The car called for a .9 when built and was superceeded to a 1.1.

    If either of those will not contain the coolant when the motor is running it is overheating.

    It really is that simple.
     
  21. smg2

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    no re-invention, just a curiosity over the 0.9 vs 1.1 bar spec and how it effects water temp.

    the car has no cooling issues at present.

    also of note the expansion tank should not be filled to the top but 16cm from the neck, below the breather pipe from the crossover tube. which means there is always air in the system.
     
  22. Rifledriver

    Rifledriver Three Time F1 World Champ

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    It subjects the pump to a couple of pounds more pressure so iffy seals fail sooner and increases the max temp a little.

    Air space....just like every other water cooling system ever made.
     
  23. dozzina

    dozzina F1 World Champ
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    I don't understand this piece of data. What is your source of information for this?

    Water, when heated, expands by some percentage of the volume. The pressure generated can be many thousands of PSI, or nothing at all, based on the expandability of the container holding it. In the case of an automobile, any expansion which drives the pressure over the cap pressure simply dribbles off into the expansion tank, where it is recovered back into the radiator when the engine cools back off.
     
  24. f355spider

    f355spider F1 World Champ
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    16cm?! Are you certain? I have always heard it should be 6cm.
     
  25. Darolls

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    Must be a misprint, at 16cm the tank would be empty.

    6cm is about right, a bit over 2 in. from the bottom of the neck.
     

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